Hydrophosphination reactions with transition metal ferrocenylphosphine complexes

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Hydrophosphination reactions with transition metal ferrocenylphosphine complexes.

The group 6 metal mono-, bis- and tris-ferrocenylphosphine complexes [M(CO)5(PH2Fc)] (1a, M = Cr; 1b, M = Mo; 1c, M = W), cis-[M(CO)4(PH2Fc)2] (2a, M = Cr; 2b, M = Mo; 2c, M = W) and fac-[M(CO)3(PH2Fc)3] (3a, M = Cr; 3b, M = Mo; 3c, M = W) [Fc = Fe(η(5)-C5H4)(η(5)-C5H5)] were prepared and fully characterised. IR and NMR spectroscopy and single-crystal X-ray diffraction analysis indicate that Fc...

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ژورنال

عنوان ژورنال: Dalton Transactions

سال: 2016

ISSN: 1477-9226,1477-9234

DOI: 10.1039/c5dt03374h